The Chinese University of Hong Kong
May
28, 2002 (Tuesday)
9:00am - 12:00noon
Room
503, Mong Man Wai Building, CUHK
Speaker |
Affiliation |
Title |
Professor M. J. Ward |
Department of Mathematics, University
of British Columbia |
(To be announced) |
Professor Xinfu Chen |
Department of Mathematics, University
of Pittsburgh |
Generation, Propagation and Annilation
of Metastable Patterns |
Professor Xiaofeng Ren |
Department of Mathematics, Utah State
University |
Block Copolymer Morphology and
Variational Calculus |
For
enquiries, please contact Prof. J. C. Wei by phone at 2609-7967 or email: wei@math.cuhk.edu.hk.
Programme
9:00 - 9:15am | Registration |
9:15 - 10:00am | |
Speaker: | Professor M. J. Ward |
Affiliation: | Department of Mathematics, University of British Columbia |
Title: | (To be announced) |
10:00 - 10:15am | Tea Break |
10:15 - 11:00am | |
Speaker: | Professor Xinfu Chen |
Affiliation: | Department of Mathematics, University of Pittsburgh |
Title: | Generation, Propagation and Annilation of Metastable Patterns |
11:00 - 11:15am | Tea Break |
11:15 - 12:00noon | |
Speaker: | Professor Xiaofeng Ren |
Affiliation: | Department of Mathematics, Utah State University |
Title: | Block Copolymer Morphology and Variational Calculus |
Abstract: | Block copolymers belong to a class of soft materials that are characterized by fluid-like disorder on the molecular scale and a high degree of morphological order at longer length scales. They are produced by joining two (in the case of diblock copolymers) or three (in the case of triblock copolymers) chemically distinct homopolymer blocks, each a linear series of identical monomers, to form long chain molecules.
In this talk I will review a density functional theory. In this theory the free energy is expressed as a functional of the order parameters of monomer densities. It is a variational problem with a nonlocal term in the integrand. I will take a diblock copolymer as an example to explain the existence of the AB lamellar phase, an ordered morphological pattern, as a free energy local minimizer, using the methods of G-convergence and energy comparison. I will also explain the structural phase transition from this ordered lamellar phase to the disordered homogeneous phase when temperature rises. Then I will discuss the lamellar phase of a triblock copolymer and some non-lamellar phases. |